Show simple item record

dc.contributor.advisorCasadonte, Dominick J.
dc.creatorMa, Wei
dc.date.accessioned2020-02-12T16:24:51Z
dc.date.available2020-02-12T16:24:51Z
dc.date.created2014-12
dc.date.issued2014-12-12
dc.date.submittedDecember 2014
dc.identifier.urihttps://hdl.handle.net/2346/85616
dc.description.abstractThe new luminescent 1-D polymeric compound [Cu(dmp)(µ-PTA)]n(NO3)n•nH2O (complex 1) (dmp = 2,9-dimethyl-1,10 phenanthroline and PTA = 1,3,5 - triaza - 7 - phosphaadamantae_) containing coordination from both phosphorous and nitrogen atoms on the phosphaadamantane and the mononuclear Cu(dmp)(PTA)2NO3 (complex 2) (phosphorus coordination only from the PTA) were prepared by reacting the Cu(I)(dmp)2 with two equivalents of PTA in a homogenous solution at room temperature. Both compounds are water-soluble and air-stable, and were characterized by single crystal X-ray diffraction, 1H and 31P NMR. Complex 1 and 2 exhibit distinct photoluminescence in the solid state, DCM solution, and frozen glass, thus providing the potential for the production of water-soluble PTA-based photovoltaic devices.
dc.format.mimetypeapplication/pdf
dc.subjectphotochemistry, Cu(I) Phenanthroline Mixed-Ligand Complexes
dc.titleSynthesis and Photophysical Studies of Novel Water-Soluble Cu(I) Phenanthroline Mixed-Ligand Complexes Containing 1,3,5-Triaza-7-phosphaadamantane
dc.typeThesis
dc.date.updated2020-02-12T16:24:51Z
dc.type.materialtext
thesis.degree.nameMaster of Science
thesis.degree.levelMasters
thesis.degree.disciplineChemistry
thesis.degree.grantorTexas Tech University
thesis.degree.departmentChemistry and Biochemistry
dc.contributor.committeeMemberWhittesey, Bruce R.


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record