tert-Butyl N-(thio­phen-2-yl)carbamate


In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intra­molecular C—H⋯O inter­actions in tandem with the tert-butyl groups render the packing of adjacent mol­ecules in the [001] direction nearly perpendicular [the angle between adjacent thio­phene rings is 74.83 (7)°]. An inter­molecular N—H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.


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compound, thiophene ring, tert-butyl groups, N-(thio­phen-2-yl)carbamate


Hsu, G. C., Singer, L. M., Cordes, D. B., & Findlater, M. (2013). tert-Butyl N-(thio­phen-2-yl)carbamate. Acta Crystallographica Section E Structure Reports Online, 69(9). https://doi.org/10.1107/s160053681302196x