Multilayer 3D Chiral Folding Polymers and Their Asymmetric Catalytic Assembly

dc.creatorTang, Yao
dc.creatorJin, Shengzhou
dc.creatorZhang, Sai
dc.creatorWu, Guan-Zhao
dc.creatorWang, Jia-Yin
dc.creatorXu, Ting
dc.creatorWang, Yu
dc.creatorUnruh, Daniel
dc.creatorSurowiec, Kazimierz
dc.creatorMa, Yanzhang
dc.creatorWang, Shiren
dc.creatorKatz, Courtney
dc.creatorLiang, Hongjun
dc.creatorLi, Yunze
dc.creatorCong, Weilong
dc.creatorLi, Guigen
dc.date.accessioned2022-03-07T16:25:31Z
dc.date.available2022-03-07T16:25:31Z
dc.date.issued2022
dc.descriptionCopyright © 2022 Yao Tang et al. Exclusive Licensee Science and Technology Review Publishing House. Distributed under a Creative Commons Attribution License (CC BY 4.0).en_US
dc.description.abstractA novel class of polymers and oligomers of chiral folding chirality has been designed and synthesized, showing structurally compacted triple-column/multiple-layer frameworks. Both uniformed and differentiated aromatic chromophoric units were successfully constructed between naphthyl piers of this framework. Screening monomers, catalysts, and catalytic systems led to the success of asymmetric catalytic Suzuki-Miyaura polycouplings. Enantio- and diastereochemistry were unambiguously determined by X-ray structural analysis and concurrently by comparison with a similar asymmetric induction by the same catalyst in the asymmetric synthesis of a chiral three-layered product. The resulting chiral polymers exhibit intense fluorescence activity in a solid form and solution under specific wavelength irradiation.en_US
dc.identifier.citationTang, Y., Jin, S., Zhang, S., Wu, G.-Z., Wang, J.-Y., Xu, T., Wang, Y., Unruh, D., Surowiec, K., Ma, Y., Wang, S., Katz, C., Liang, H., Li, Y., Cong, W., & Li, G. (2022). Multilayer 3D Chiral Folding Polymers and Their Asymmetric Catalytic Assembly. Research, 2022, 9847949. https://doi.org/10.34133/2022/9847949en_US
dc.identifier.urihttps://doi.org/10.34133/2022/9847949
dc.identifier.urihttps://hdl.handle.net/2346/88848
dc.language.isoengen_US
dc.subjectPolymersen_US
dc.subjectChiralityen_US
dc.subjectOligomersen_US
dc.titleMultilayer 3D Chiral Folding Polymers and Their Asymmetric Catalytic Assemblyen_US
dc.typeArticleen_US

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