Controlling topology within halogen-bonded networks by varying the regiochemistry of the cyclobutane-based nodes
dc.creator | Dunning, Taylor J. | |
dc.creator | Unruh, Daniel K. (TTU) | |
dc.creator | Bosch, Eric | |
dc.creator | Groeneman, Ryan H. | |
dc.date.accessioned | 2023-05-11T18:49:01Z | |
dc.date.available | 2023-05-11T18:49:01Z | |
dc.date.issued | 2021 | |
dc.description | © 2021 by the authors. Licensee MDPI, Basel, Switzerland. cc-by | |
dc.description.abstract | The formation of a pair of extended networks sustained by halogen bonds based upon two regioisomers of a photoproduct, namely rctt-1,3-bis(4-pyridyl)-2,4-bis(phenyl)cyclobutane (ht-PP) and rctt-1,2-bis(4-pyridyl)-3,4-bis(phenyl)cyclobutane (hh-PP), that have varied topology is reported. These networks are held together via I· · · N halogen bonds between the photoproduct and the halogen-bond donor 1,4-diiodoperchlorobenzene (C6 I2 Cl4). The observed topology in each solid is controlled by the regiochemical position of the halogen-bond accepting 4-pyridyl group. This paper demonstrates the ability to vary the topology of molecular networks by altering the position of the halogen bond acceptor within the cyclobutane-based node. | |
dc.identifier.citation | Dunning, T.J., Unruh, D.K., Bosch, E., & Groeneman, R.H.. 2021. Controlling topology within halogen-bonded networks by varying the regiochemistry of the cyclobutane-based nodes. Molecules, 26(11). https://doi.org/10.3390/molecules26113152 | |
dc.identifier.uri | https://doi.org/10.3390/molecules26113152 | |
dc.identifier.uri | https://hdl.handle.net/2346/93458 | |
dc.language.iso | eng | |
dc.subject | Crystal engineering | |
dc.subject | Halogen bonding | |
dc.subject | Organic solid state | |
dc.subject | Topology | |
dc.title | Controlling topology within halogen-bonded networks by varying the regiochemistry of the cyclobutane-based nodes | |
dc.type | Article |
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