Aggregation-induced polarization (AIP) of derivatives of BINOL and BINAP

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dc.creatorTang, Yao (TTU)
dc.creatorYuan, Qingkai (TTU)
dc.creatorWang, Yu
dc.creatorZhang, Sai (TTU)
dc.creatorWang, Jia-Yin
dc.creatorJin, Shengzhou
dc.creatorXu, Ting
dc.creatorPan, Junyi
dc.creatorGuilbeau, Collin Ray (TTU)
dc.creatorPleasant, Alyssa Jenae (TTU)
dc.creatorLi, Guigen (TTU)
dc.date.accessioned2023-03-03T23:29:57Z
dc.date.available2023-03-03T23:29:57Z
dc.date.issued2022
dc.descriptionThis article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en_US
dc.description.abstractThe relationship between optical rotations of small chiral molecules with water% in THF has been established. The typical aggregation co-solvent systems resulted in optical rotation amplification and adjustment, defined as aggregation-induced polarization (AIP). The AIP work can serve as a new tool to determine molecular aggregation, especially for those that cannot display aggregation-induced emission (AIE). Therefore, AIP and AIE are anticipated to complement each other. In addition, AIP can also serve as a new transmission tool providing adjusting right- or left-hand polarized lights of a series of individual wavelengths. Since chiral phosphine derivatives are among the most important ligands, this work would benefit research using chiral aggregates to control asymmetric synthesis and catalysts. Therefore, it will find many applications in chemical and materials sciences.en_US
dc.identifier.citationRSC Adv., 2022,12, 29813-29817en_US
dc.identifier.urihttps://doi.org/10.1039/D2RA05597J
dc.identifier.urihttps://hdl.handle.net/2346/91035
dc.language.isoengen_US
dc.subjectOptical rotationen_US
dc.subjectChiralityen_US
dc.subjectAggregation-induced polarization (AIP)en_US
dc.subjectCo-solvent systemsen_US
dc.subjectAggregation-induced emission (AIE)en_US
dc.subjectChiral phosphine derivativesen_US
dc.subjectAsymmetric synthesisen_US
dc.subjectCircularly polarized luminescence (CPL)en_US
dc.titleAggregation-induced polarization (AIP) of derivatives of BINOL and BINAPen_US
dc.typeArticleen_US

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