Four-layer folding framework: design, GAP synthesis, and aggregation-induced emission

Simple item page
dc.creatorZhang, Sai (TTU)
dc.creatorChen, Daixiang
dc.creatorWang, Jia Yin
dc.creatorYan, Shenghu
dc.creatorLi, Guigen (TTU)
dc.date.accessioned2023-09-11T21:07:15Z
dc.date.available2023-09-11T21:07:15Z
dc.date.issued2023
dc.descriptionCopyright © 2023 Zhang, Chen, Wang, Yan and Li. cc-by
dc.description.abstractThe design and synthesis of a type of [1 + 4 + 2] four-layer framework have been conducted by taking advantage of Suzuki–Miyaura cross-coupling and group-assisted purification (GAP) chemistry. The optimized coupling of double-layer diboronic esters with 1-bromo-naphth-2-yl phosphine oxides resulted in a series of multilayer folding targets, showing a broad scope of substrates and moderate to excellent yields. The final products were purified using group-assisted purification chemistry/technology, achieved simply by washing crude products with 95% EtOH without the use of chromatography and recrystallization. The structures were fully characterized and assigned by performing X-ray crystallographic analysis. UV–vis absorption, photoluminescence (PL), and aggregation-induced emission (AIE) were studied for the resulting multilayer folding products.
dc.identifier.citationZhang, S., Chen, D., Wang, J.-Y., Yan, S., & Li, G.. 2023. Four-layer folding framework: design, GAP synthesis, and aggregation-induced emission. Frontiers in Chemistry, 11. https://doi.org/10.3389/fchem.2023.1259609
dc.identifier.urihttps://doi.org/10.3389/fchem.2023.1259609
dc.identifier.urihttps://hdl.handle.net/2346/96005
dc.language.isoeng
dc.subjectAIE
dc.subjectGAP chemistry
dc.subjectmultilayer folding molecules
dc.subjectphosphine oxides
dc.subjectSuzuki–Miyaura coupling
dc.titleFour-layer folding framework: design, GAP synthesis, and aggregation-induced emission
dc.typeArticle

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
Main article with TTU Libraries cover page.pdf
Size:
1.91 MB
Format:
Adobe Portable Document Format
Download

Collections

Faculty Research