Halogen-bonded co-crystal containing 1,3-diiodo-perchlorobenzene and the photoproduct rtct-tetrakis(pyridin-4-yl)cyclobutane resulting in a zigzag topology
dc.creator | Bosch, Eric | |
dc.creator | Unruh, Daniel K. (TTU) | |
dc.creator | Santana, Carlos L. | |
dc.creator | Groeneman, Ryan H. | |
dc.date.accessioned | 2023-06-13T18:59:45Z | |
dc.date.available | 2023-06-13T18:59:45Z | |
dc.date.issued | 2023 | |
dc.description | © 2023 International Union of Crystallography. All rights reserved. cc-by | |
dc.description.abstract | The formation and crystal structure of a zigzag network held together by I• • •N halogen bonds is reported. In particular, the halogen-bond donor is 1,3-diiodoperchlorobenzene (C6I2Cl4) while the acceptor is the photoproduct rtct-tetrakis(pyridin-4-yl)cyclobutane (TPCB). Curiously, within the resulting co-crystal (C6I2Cl4)•(TPCB), the photoproduct accepts only two halogen bonds between neighbouring 4-pyridyl rings and as a result behaves as a bent two-connected node rather than the expected four-connected centre. In addition, the photoproduct, TPCB, is also found to engage in C—H• • •N hydrogen bonds, forming an extended zigzag chain. | |
dc.identifier.citation | Bosch, E., Unruh, D.K., Santana, C.L., & Groeneman, R.H.. 2023. Halogen-bonded co-crystal containing 1,3-diiodo-perchlorobenzene and the photoproduct rtct-tetrakis(pyridin-4-yl)cyclobutane resulting in a zigzag topology. Acta Crystallographica Section E: Crystallographic Communications, 79(Pt 3). https://doi.org/10.1107/S2056989023001408 | |
dc.identifier.uri | https://doi.org/10.1107/S2056989023001408 | |
dc.identifier.uri | https://hdl.handle.net/2346/94074 | |
dc.language.iso | eng | |
dc.subject | co-crystal | |
dc.subject | cyclobutane | |
dc.subject | halogen bonding | |
dc.subject | organic solid state | |
dc.subject | photoproduct | |
dc.subject | zigzag network | |
dc.subject | [2 + 2] cycloaddition reaction | |
dc.title | Halogen-bonded co-crystal containing 1,3-diiodo-perchlorobenzene and the photoproduct rtct-tetrakis(pyridin-4-yl)cyclobutane resulting in a zigzag topology | |
dc.type | Article |
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