Triple-Columned and Multiple-Layered 3D Polymers: Design, Synthesis, Aggregation-Induced Emission (AIE), and Computational Study

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dc.creatorWu, Guanzhao
dc.creatorLiu, Yangxue
dc.creatorYang, Zhen
dc.creatorMa, Liulei
dc.creatorTang, Yao
dc.creatorZhao, Xianliang
dc.creatorRouh, Hossein
dc.creatorZheng, Qixuan
dc.creatorZhou, Peng
dc.creatorWang, Jia-Yin
dc.creatorSiddique, Farhan
dc.creatorZhang, Sai
dc.creatorJin, Shengzhou
dc.creatorUnruh, Daniel
dc.creatorAquino, Adelia J. A.
dc.creatorLischka, Hans
dc.creatorHutchins, Kristin M.
dc.creatorLi, Guigen
dc.date.accessioned2022-03-14T19:17:43Z
dc.date.available2022-03-14T19:17:43Z
dc.date.issued2021
dc.descriptionCopyright © 2021 Guanzhao Wu et al. Exclusive Licensee Science and Technology Review Publishing House. Distributed under a Creative Commons Attribution License (CC BY 4.0).en_US
dc.description.abstractConjugated polymers and oligomers have great potentials in various fields, especially in materials and biological sciences because of their intriguing electronic and optoelectronic properties. In recent years, the through-space conjugation system has emerged as a new assembled pattern of multidimensional polymers. Here, a novel series of structurally condensed multicolumn/multilayer 3D polymers and oligomers have been designed and synthesized through one-pot Suzuki polycondensation (SPC). The intramolecularly stacked arrangement of polymers can be supported by either X-ray structural analysis or computational analysis. In all cases, polymers were obtained with modest to good yields, as determined by GPC and 1H-NMR. MALDI-TOF analysis has proven the speculation of the step-growth process of this polymerization. The computational study of ab initio and DFT calculations based on trimer and pentamer models gives details of the structures and the electronic transition. Experimental results of optical and AIE research confirmed by calculation indicates that the present work would facilitate the research and applications in materials.en_US
dc.identifier.citationWu, G., Liu, Y., Yang, Z., Ma, L., Tang, Y., Zhao, X., Rouh, H., Zheng, Q., Zhou, P., Wang, J.-Y., Siddique, F., Zhang, S., Jin, S., Unruh, D., Aquino, A. J., Lischka, H., Hutchins, K. M., & Li, G. (2021). Triple-columned and multiple-layered 3D polymers: Design, synthesis, aggregation-induced emission (AIE), and computational study. Research, 2021, 1–13. https://doi.org/10.34133/2021/3565791en_US
dc.identifier.urihttps://doi.org/10.34133/2021/3565791
dc.identifier.urihttps://hdl.handle.net/2346/88857
dc.language.isoengen_US
dc.subjectPolymersen_US
dc.titleTriple-Columned and Multiple-Layered 3D Polymers: Design, Synthesis, Aggregation-Induced Emission (AIE), and Computational Studyen_US
dc.typeArticleen_US

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